Hazardous Material Identification Guide (HMIG)
  Material Safety Data Sheet (MSDS)
  Storage Colour Code
     
     
HAZARDOUS MATERIAL IDENTIFICATION GUIDE

 

HMIG is a comprehensive hazard communication programme.

HMIG communicates hazard information to the use of colour, numbers, letter of alphabets and symbols. In this system health (blue), flammability (red) and reactivity (yellow) are coded with colour and numbers, whereas personal protective equipment (white) is with letter of alphabet and symbols.

The national fire protection association ('NFPA'- USA) has developed 'Fire Diamond' in which white section indicates fire protection. The national paints and coating association (NPCA-USA) has developed HMIS in which white section indicates personal protective equipment. All other sections like health (blue), flammability (red) and reactivity (yellow) remain same in both the systems. Laboratory chemicals are usually operated with limited quantities in small packing, which has a limited risk of fire and hence preference is given to protective equipment in HMIG in our labels.


Types of hazards.The HMIG is sub-divided into four general categories,

  • health (blue)
  • flammability (red)
  • reactivity (yellow)
  • protective equipment (white)

you can find hazard ratings for common laboratory chemicals in our labels and MSDSs. For each calss of materials here are some handy guidelines and examples to help you assign or understand a hazard rating.

 

SAFETY WITH AWARENESS

Every employer has an overall responsibility to provide their employees with a safe and healthful workplace. Hazard communication is an important part of this responsibility.

Hazard Communication Standard : (HCS)

According to "The Occupational Safety and Health Administration" (OHSA) millions of workers are potentially exposed to one or more chemical hazards. There are an estimated 5,75,000 existing chemical products and hundred of new ones introduced annually. This poses a potential problem for exposed workers and their employers.

Chemical exposure cause or contribute to many serious health effects including such "acute" or immediate effects as difficulty in breathing, respiratory failure, rashes or burns to the skin and eyes, headaches and dizziness. Repeated over exposure to certain chemicals can leave to other "chronic" effects such as heart ailments, kidney and lung damage, sterility and cancer. Some chemicals may also be safety hazards and have the potential to cause fire and explosions or other serious accidents.

The HCS establishes uniform requirements to make sure that the hazards of all chemicals as work places are evaluated and that this hazard information is given to employers and employees. Chemical manufacturers convey the hazard information they learn from the evaluations to downstream employees by means of labels on containers and MSDSs.

The hazard communication programme ensures that all employers receive the information they need to inform and train their employees properly and to design and put in place employee protection programmes. It also provides necessary hazard information to employees, so they can participate in, an support, the protective measures in place at their workplaces.

In our view of awareness "downstream flow of information", which means that producers of chemicals have primary responsibility for generating and disseminating information and that users of chemicals must obtain the information and transmit it to their own employees. In general, it works like this

  • Chemical Manufacturer Determine the hazards of each product
  • Chemical Manufacturers / Distributors Communicate the hazard information and associated protective measures downstream to customers thorugh labels and MSDSs.
  • Employers Identify and list hazardous chemicals in their workplaces. Obtain MSDSs and labels for each hazardous chemical. Develop and implement a written hazard communication programme, including labels, MSDSs, and employee training on the list of Chemicals, MSDSs, and label information.

Communicate hazard information to their employees through labels, MSDSs, and formal training programme. HMIG is designed to help employers inform employees and comply with the HCS

The hazard communication portion of the HMIG program communicates information on :

Chemical identity
Chronic and acute health hazards
Degree of flammability
Reactivity hazards, and
Proper personal protective equipment.

Chemical identity id conveyed by chemical or common names, code numbers or other descriptive terms which clearly identify the material for hazard evaluation purposes. The severity of any acute health, flammability and reactivity hazards is communicated by numerical ratings.

Personal protective equipment is designated by an alphabetical designation, with items identified either as groups of complementary equipment or as individual pieces of safety wear.

 
HEALTH
4 Extreme : Highly toxic material On very short exposure could cause death or major residual injury even though prompt medical treatment is given.
A known or suspected human carcinogen, mutagen or teratogen.
3 Serious : Toxic Material May cause serious temporary or residual injury on short term exposure even though prompt medical treatment is given. A known or suspected small animal carcinogen, mutagen or teratogen.
2 Moderate : Moderately toxic material Intense or continued exposure could cause temporary incapacitation or possible residual injury, unless prompt medical treatment is given.
1 Slight : Slightly toxic material May cause irritation but only minor residual injury even without treatment. Recognized innocuous material when used with responsible care.
0 Minimum : No chemical is without some degree of toxicity
 
FLAMMABILITY HAZARD
4 Extreme : Extremely Flammable Flash point below 20oC.
3 Serious : Flammable Vapourises readily and can be ignited unser almost all ambient conditions. May form explosive mixtures with or burn rapidly in air. May burn rapidly due to self-contained oxygen. May ignite spontaneously in air. Flash point at or above 20oC but less than 35oC.
2 Moderate : Combustible Must be moderately heated or exposed to relatively high temperatures for ignition to Occur. Solids with readily give off flammable vapours. Flash point at or above 35oC but less than 92oC
1 Slight : Slightly combustible Must be preheated for ignition to occur. Will burn in air when exposed at 815oC for 5 minutes Flash point at or above 92oC.
0 Minimum : Will not burn Will not exhibit a flash point Will not burn in air when exposed at 815oC for 5 minutes
 
REACTIVITY HAZARD
4 Extreme : Can explode or decompose violently at normal temperature and pressure. Can undergo a violent self-accelerating exothermic reaction with common materials or by itself. May be sensitive to mechanical or local thermal shock at normal temperature and pressure.
3 Serious : Can detonate or explode but requires a strong initiating force or confined heating before initiation. Readily promotes oxidation with combustible materials and may cause fires Is sensitive to thermal or mechanical shock at elevated temperatures. May react explosively with water without requiring heat or confinement.
2 Moderate : Normally unstable and readily undergoes violent change but does not detonate. May undergo chemical change with rapid release of energy at normal temperature and pressure. May react violently with water. Forms potentially explosive mixtures with water.
1 Slight : Normally stable material which can become instable at high temperature and pressure.
0 Minimum : Normally stable material which is not reactive with water.
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"STC" a company committed to ENVIRONMENT & SAFETY WITH AWARNESS. In absence of lak like "Right to Know" Information is not circulated in general.

A unique file of "MATERIAL SAFETY DATA SHEETS" containing following products, alogn with a literature "Preparing & Understanding MSDSs" is available for your persual

 

Acetic Acid Glacial Acetone
Hydrochloric Acid Acetonitrile
Nitric Acid Benzene
Sulphuric Acid Carbon tetrachloride
Ammonia solution 25% Chloroform
Hydrogen peroxide 30% Diethyl ether
Formaldehyde Hexene
Sodium Hydroxide Methanol
Barium Nitrate Petroleum ether 40-60 C
Cupric Sulphate iso-propyl alcohol
Lead Nitrate Toluene
Mercuric Chloride Xylene

 

Above File will be sent to the consumer on request only. If you need MSDS of any other product marketed by us, your can Fill out the Form or Send an email at : samir@samirtech.com

 

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Flammability hazard
Store in a area segregated for flamable reagents

 

Health hazards
Toxic if inhalted,ingested or absorbed through skin. STORE in a secure poison area.

 

Reactivity hazard
Oxidising reagents May react violently with air, water or other substances. STORE away from flammable and combustible material.

  Contact hazard
Corrosive May harm skin, eyes, mucous membranes. Store away from red, yellow and blue coded reagents. STORE in a CORROSION - proof area
  For General chemical storage
Presents no more than moderate hazards in any of categories above.
  Exception
Reagents in compatible with other reagent of any / same colour bar. STORE SEPARATELY.
 
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